Allylboronic acid pinacol ester
- Product Name
- Allylboronic acid pinacol ester
- CAS No.
- 72824-04-5
- Chemical Name
- Allylboronic acid pinacol ester
- Synonyms
- 2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;4,4,5,5-Tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane;AKOS BRN-1082;PINACOL ALLYLBORONATE;Allyl pinacol boronate;Pinacolyl 2-propenylboronate;Allylboronic acid pinacolate;Allylboronic acid picol ester;ALLYLBORONIC ACID PINACOL ESTER;Allylboronic acid piracol ester
- CBNumber
- CB7169827
- Molecular Formula
- C9H17BO2
- Formula Weight
- 168.04
- MOL File
- 72824-04-5.mol
Allylboronic acid pinacol ester Property
- Boiling point:
- 50-53 °C/5 mmHg (lit.)
- Density
- 0.896 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.4268(lit.)
- Flash point:
- 115 °F
- storage temp.
- 2-8°C
- solubility
- Chloroform, Methanol (Slightly)
- form
- Liquid
- color
- Clear colorless
- Water Solubility
- Not miscible or difficult to mix in water.
- BRN
- 4244068
- CAS DataBase Reference
- 72824-04-5(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 10-36/37/38
- Safety Statements
- 26-36
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 3
- Hazard Note
- Irritant
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29310095
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242Use only non-sparking tools.
P243Take precautionary measures against static discharge.
N-Bromosuccinimide Price
- Product number
- 324647
- Product name
- Allylboronic acid pinacol ester
- Purity
- 97%
- Packaging
- 1g
- Price
- $50.1
- Updated
- 2024/03/01
- Product number
- 324647
- Product name
- Allylboronic acid pinacol ester
- Purity
- 97%
- Packaging
- 10g
- Price
- $308
- Updated
- 2024/03/01
- Product number
- A2157
- Product name
- 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine)
- Purity
- >96.0%(GC)
- Packaging
- 1g
- Price
- $41
- Updated
- 2024/03/01
- Product number
- A2157
- Product name
- 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine)
- Purity
- >96.0%(GC)
- Packaging
- 5g
- Price
- $115
- Updated
- 2024/03/01
- Product number
- L16232
- Product name
- Allylboronic acid pinacol ester, 98+%
- Packaging
- 1g
- Price
- $37.65
- Updated
- 2024/03/01
Allylboronic acid pinacol ester Chemical Properties,Usage,Production
Chemical Properties
Clear corless liquid
Uses
Allylboronic acid pinacol ester reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield. Homoallylic alcohols can also be formed by allylboration of aldehydes. It is a reagent used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis, intermolecular radical additions, allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids, cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes, nucleic acid-templated energy transfer leading to a photorelease reaction and stereoselective indium-catalyzed Hosomi-Sakurai reactions.
Uses
Allylboronic acid pinacol ester can act as reagent used for Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis; Intermolecular radical additions; Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids and Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes ; Nucleic acid-templated energy transfer leading to a photorelease reaction .
Allylboronic acid pinacol ester Preparation Products And Raw materials
Raw materials
Preparation Products
Allylboronic acid pinacol ester Suppliers
View Lastest Price from Allylboronic acid pinacol ester manufacturers
- Product
- Allylboronic acid pinacol ester 72824-04-5
- Price
- US $34.00-1.20/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-08
- Product
- Allylboronic acid pinacol ester 72824-04-5
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-10
- Product
- Allylboronic acid pinacol ester 72824-04-5
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09